MoO2Cl2(dmf)2-catalyzed domino reactions of ω-nitro alkenes to 3,4-dihydro-2H-1,4-benzothiazines and other heterocycles

Publikations-Art
Zeitschriftenbeitrag (peer-reviewed)
Autoren
Malakar, C. C.; Merisor, E.; Conrad, J.; Beifuss, U.
Erscheinungsjahr
2010
Veröffentlicht in
Synlett
DOI
10.1002/chin.201044180
Seite (von - bis)
1766-1770
Abstract

As exemplified by the transformation of allyl 2-nitrophenyl thioethers to 3,4-dihydro-2H-1,4-benzothiazines, the reductive cyclization of w-nitro alkenes to satd. N-heterocycles can be performed with high selectivity and high yields using a combination of MoO2Cl2(dmf)2 as a catalyst and Ph3P as reducing agent.

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