Short total synthesis of the spiro[4.5]decane sesquiterpene (-)-gleenol

Publikations-Art
Zeitschriftenbeitrag
Autoren
Oesterreich, K.; Spitzner, D
Erscheinungsjahr
2002
Veröffentlicht in
Tetrahedron
Band/Volume
58/21
Seite (von - bis)
4331-4334
Abstract

The spirocyclic sesquiterpene (-)-gleenol (I) was prepd. in five steps starting from (-)-menthone via a di-olefin. The final spiro-ring system was made using the olefin metathesis reaction. The resulting ketone was selectively reduced to the natural product.

Beteiligte Einrichtungen