Unexpected Lewis acid mediated reactions of 1-arylbut-3-en-1-ols with trimethyl orthoformate - A new synthesis of homoallyl ethers and chlorides
- Publikations-Art
- Zeitschriftenbeitrag (peer-reviewed)
- Autoren
- Merisor, E.; Conrad, J.; Malakar, C.C.; Beifuss, U.
- Erscheinungsjahr
- 2008
- Veröffentlicht in
- Synlett
- Verlag
- Georg Thieme Verlag
- DOI
- 10.1055/s-2008-1042928
- Seite (von - bis)
- 903-907
1-Arylbut-3-en-1-ols react with HC(OMe)3 in the presence of Lewis acids like InCl<sub>3</sub>, BiCl<sub>3</sub>, TiCl<sub>4</sub>, or BF<sub>3</sub>.OEt<sub>2</sub> to provide homoallyl ethers or homoallyl chlorides in high yields.