One-pot reactions: enantiomerically pure bicyclo[5.3.1]undecanes; synthesis of a taxoid compound
- Publikations-Art
- Zeitschriftenbeitrag
- Autoren
- Gutke, H.-J.; Braun, N. A.; Spitzner, D.
- Erscheinungsjahr
- 2004
- Veröffentlicht in
- Tetrahedron
- Band/Volume
- 60/37
- Seite (von - bis)
- 8137-8141
Reaction of C-2 substituted cyclohexenone with an enantiomerically pure a-bromopentenoate leads to enantiopure tricyclooctane, which can be transformed into a taxoid like compd. having the typical bicyclo[5.3.1]undecane skeleton.