Triethyl phosphite mediated domino reaction: direct conversion of ϖ-nitroalkenes into N-heterocycles

Publikations-Art
Zeitschriftenbeitrag (peer-reviewed)
Autoren
Merisor, E.; Conrad, J.; Klaiber, I.; Mika, S.; Beifuss, U.
Erscheinungsjahr
2007
Veröffentlicht in
Angew. Chem. Int. Ed.
Band/Volume
46/18
DOI
10.1002/anie.200605260
Seite (von - bis)
3353-3355
Abstract

The first domino reaction in which ϖ-nitroalkenes are converted into satd. N-heterocycles is described. The reductive cyclization reaction mediated by tri-Et phosphite allows access to substituted 3,4-dihydro-2H-1,4-benzoxazines, 1,2,3,4-tetrahydroquinoxalines, and 1,2,3,4-tetrahydroquinolines.

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