A simple synthesis of a functionalized tricyclo[5.2.2.01,5]undecene as a synthon for isoeremolactone

Publication Type
Journal contribution
Authors
Weber, W.; Spitzner, D.; Kraus, W.
Year of publication
1980
Published in
J. Chem. Soc., Chem. Commun.
Band/Volume
24/
Page (from - to)
1212-3
Abstract

The ester I, a synthon for the diterpene isoeremolactone, was prepd. (80%) from the racemic ketone II by sequential double Michael addn. of Me acrylate, thioacetalization, redn., tolylsulfonylation, and solvolysis.

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