Crystal structure of 3-hydroxy-8-methyltricyclo[5.3.1.03,8]undec-5-en-2-one, C<sub>12</sub>H<sub>16</sub>O<sub>2</sub>
- Publication Type
- Journal contribution
- Authors
- Oesterreich, K.; Spitzner, D.; Oeckler, O.; Simon, A.
- Year of publication
- 2001
- Published in
- Zeitschrift fuer Kristallographie - New Crystal Structures
- Band/Volume
- 216/2
- Page (from - to)
- 293-294
The title compd. is monoclinic, space group P21/c, a 12.476(3), b 11.134(2), c 14.100(3) .ANG., β 149.49(3)° , Z = 4, Rgt(F) = 0.042, wRref(F2) = 0.112, T = 93 K. At. coordinates are given. There are dimers stabilized by 2 H bonds from O(1) and O(2) of 1 mol. to O(2) and O(1) of the other mol., resp. The center of inversion lies in the center of gravity of these 4 O atoms. The arrangement of the dimers is rather closed packed, no voids accessible for solvent mols. are present in the structure.