Resin-bound anionically induced Domino reactions; synthesis of functionalized carbocyclic compounds

Publication Type: Journal contribution
Authors: Gutke, H.-J.; Spitzner, D.
Year of publication: 1999
Published in: Tetrahedron
Band/Volume: 55/13
Page (from - to): 3931-3936

Abstract

The anionically induced domino reaction of resin-bound Li-dienolate with an α-halo-α,β-unsatd. ester gave the corresponding immobilized tricyclo[3.2.1.02,7]octane, which can be olefinated or oxidized. The cycles are cleaved from the resin by acid.

Involved institutions

Institute of Chemistry
Bioorganic Chemistry